# 1 "/u/exp/stan/nmr/lists/pp/invietgpsi" ;invietgpsi ;avance-version ;2D H-1/X correlation via double inept transfer ; using sensitivity improvement ;phase sensitive using Echo/Antiecho-TPPI gradient selection ;with decoupling during acquisition ;using trim pulses in inept transfer ;A.G. Palmer III, J. Cavanagh, P.E. Wright & M. Rance, J. Magn. ; Reson. 93, 151-170 (1991) ;L.E. Kay, P. Keifer & T. Saarinen, J. Am. Chem. Soc. 114, ; 10663-5 (1992) ;J. Schleucher, M. Schwendinger, M. Sattler, P. Schmidt, O. Schedletzky, ; S.J. Glaser, O.W. Sorensen & C. Griesinger, J. Biomol. NMR 4, ; 301-306 (1994) # 1 "/u/exp/stan/nmr/lists/pp//Avance.incl" ;Avance.incl ; ;version 99/08/02 # 19 "/u/exp/stan/nmr/lists/pp/invietgpsi" # 1 "/u/exp/stan/nmr/lists/pp//Grad.incl" ;Grad.incl - include file for Gradient Spectroscopy ;avance-version ;version 99/02/19 define list EA= # 20 "/u/exp/stan/nmr/lists/pp/invietgpsi" # 1 "/u/exp/stan/nmr/lists/pp//Delay.incl" ;Delay.incl - include file for commonly used delays ;avance-version ;version 99/02/19 ;general delays define delay DELTA define delay DELTA1 define delay DELTA2 define delay DELTA3 define delay DELTA4 define delay DELTA5 define delay DELTA6 define delay DELTA7 define delay DELTA8 define delay TAU define delay TAU1 define delay TAU2 define delay TAU3 define delay TAU4 define delay TAU5 ;delays for centering pulses define delay CEN_HN1 define delay CEN_HN2 define delay CEN_HN3 define delay CEN_HC1 define delay CEN_HC2 define delay CEN_HC3 define delay CEN_HC4 define delay CEN_CN1 define delay CEN_CN2 ;loop counters define loopcounter COUNTER define loopcounter SCALEF define loopcounter FACTOR1 define loopcounter FACTOR2 define loopcounter FACTOR3 # 21 "/u/exp/stan/nmr/lists/pp/invietgpsi" "p2=p1*2" "p4=p3*2" "d0=3u" "d4=1s/(cnst2*4)" "d11=30m" "d13=3u" "DELTA=p16+d16+50u+p2+d0*2" "DELTA1=d13+p16+d16+4u" "l3=(td1/2)" 1 ze d11 pl12:f2 2 d1 do:f2 6m 3 d11 18m 4 (p1 ph1) d4 pl2:f2 (p2 ph1) (p4 ph6):f2 d4 p28 ph1 d13 (p1 ph2) (p3 ph3):f2 d0 p2 ph7 d0 50u setnmr2|0 setnmr0|34 p16:gp1*EA d16 (p4 ph4):f2 DELTA (p1 ph1) (p3 ph4):f2 d24 (p2 ph1) (p4 ph1):f2 d24 (p1 ph2) (p3 ph5):f2 d4 (p2 ph1) (p4 ph1):f2 d4 (p1 ph1) DELTA1 (p2 ph1) d13 p16:gp2 d16 pl12:f2 4u setnmr2^0 setnmr0^34 go=2 ph31 cpd2:f2 d1 do:f2 wr #0 if #0 zd 3m ip5 igrad EA 3m ip5 lo to 3 times 2 d11 id0 3m ip3 3m ip3 3m ip6 3m ip6 3m ip31 3m ip31 lo to 4 times l3 exit ph1=0 ph2=1 ph3=0 2 ph4=0 0 2 2 ph5=1 1 3 3 ph6=0 ph7=0 0 2 2 ph31=0 2 2 0 ;pl1 : f1 channel - power level for pulse (default) ;pl2 : f2 channel - power level for pulse (default) ;pl12: f2 channel - power level for CPD/BB decoupling ;p1 : f1 channel - 90 degree high power pulse ;p2 : f1 channel - 180 degree high power pulse ;p3 : f2 channel - 90 degree high power pulse ;p4 : f2 channel - 180 degree high power pulse ;p16: homospoil/gradient pulse ;p28: f1 channel - trim pulse ;d0 : incremented delay (2D) [3 usec] ;d1 : relaxation delay; 1-5 * T1 ;d4 : 1/(4J)XH ;d11: delay for disk I/O [30 msec] ;d13: short delay [3 usec] ;d16: delay for homospoil/gradient recovery ;d24: 1/(4J)XH for XH ; 1/(8J)XH for all multiplicities ;cnst2: = J(XH) ;l3: loop for phase sensitive 2D using E/A method : l3 = td1/2 ;in0: 1/(2 * SW(X)) = DW(X) ;nd0: 2 ;NS: 1 * n ;DS: >= 16 ;td1: number of experiments ;MC2: echo-antiecho ;cpd2: decoupling according to sequence defined by cpdprg2 ;pcpd2: f2 channel - 90 degree pulse for decoupling sequence ;use gradient ratio: gp 1 : gp 2 ; 80 : 20.1 for C-13 ; 80 : 8.1 for N-15 ;for z-only gradients: ;gpz1: 80% ;gpz2: 20.1% for C-13, 8.1% for N-15 ;use gradient files: ;gpnam1: SINE.100 ;gpnam2: SINE.100